Adsorption and Catalysis Effects of LaMnO<sub>3</sub> Nanosheets for High‐Performance Li–S Batteries

In this article, an effective redox regulation strategy of Li–S batteries is illustrated by introducing a unique petal‐like LaMnO 3 nanosheet (LMO‐NS) into the sulfur cathode. It is found that the LMO‐NS with abundant active sites offers strong chemical affinity toward the sulfur species, which play key roles in immobilizing the produced polysulfides during charge/discharge operation and then accelerating their redox conversion. Consequently, the Li–S reaction kinetics is remarkably boosted and the polysulfide shuttle is greatly alleviated owing to the adsorption‐catalysis effects of the LMO‐NS, which endows the composite cathode with increased reversible capacity and improved cycle and rate capability.

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Publication Details

Journal
Energy Technology
Published
2024-10-07
DOI
https://doi.org/10.1002/ente.202401373
Primary Topic
Advanced Battery Materials and Technologies
Type
article
Field-Weighted Citation Impact
0.00

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Adsorption and Catalysis Effects of LaMnO3 Nanosheets for High‐Performance Li–S Batteries

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article

Adsorption and Catalysis Effects of LaMnO3 Nanosheets for High‐Performance Li–S Batteries

Yitian Ma, Shuliang Luo, Yan Yuan, Cong Li, Xiao Xiao, Ben Zhou, H. J. Lü, Yihang Su
article en

Abstract

In this article, an effective redox regulation strategy of Li–S batteries is illustrated by introducing a unique petal‐like LaMnO 3 nanosheet (LMO‐NS) into the sulfur cathode. It is found that the LMO‐NS with abundant active sites offers strong chemical affinity toward the sulfur species, which play key roles in immobilizing the produced polysulfides during charge/discharge operation and then accelerating their redox conversion. Consequently, the Li–S reaction kinetics is remarkably boosted and the polysulfide shuttle is greatly alleviated owing to the adsorption‐catalysis effects of the LMO‐NS, which endows the composite cathode with increased reversible capacity and improved cycle and rate capability.

Energy TechnologyVol. 13(7)
Xi'an University of Science and Technology (CN), Xi'an University of Architecture and Technology (CN), Guangdong Ocean University (CN)
Basic and Applied Basic Research Foundation of Guangdong Province
Openalex Percentile: Top 85%
Advanced Battery Materials and Technologies
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