Femtosecond optical vortex-induced flower-shaped surface relief structures in an azo-polymer film

We study the formation of surface relief structures in azo-polymers generated via two-photon induced photoisomerization using a femtosecond near-infrared optical vortex laser beam. These structures exhibit exotic flower-like shapes with petals along the azimuthal direction, and they are formed from spatial mode instability, which is associated with third-order nonlinear effects in the azo-polymer. This process is a unique and exotic interaction between light and matter, which may be applied to the development of advanced optical data storage technologies. Here, an additional degree of freedom is offered by the number of formed petals, which themselves are a function of the topological charge of the optical vortex beam.