Complex Implications of Translational Invariance in Polymer Field Theory
The behavior of complex-Langevin field-theoretic simulations (CL-FTSs) of polymer liquids is sensitive to the nature of saddle-point field configurations, which are solutions of self-consistent field theory (SCFT). Recent work [Kang et al. Macromolecules 2024, 57, 3850] has shown that SCFT saddle-points with real fields are generally not isolated solutions but rather members of a low-dimensional family of continuously connected complex-valued saddle-points sharing the same Hamiltonian value. We show that this behavior is a natural consequence of the analyticity and translational invariance of the Hamiltonian, which together demand its invariance under generalized translations by displacements with complex components. We also present a numerical algorithm that minimizes the deleterious effects of this generalized symmetry on the stability of CL-FTSs.
Authors
- Jaeup U. Kim (ORCID: https://orcid.org/0000-0002-2853-2784)
- James D. Willis (ORCID: https://orcid.org/0000-0003-1441-9403)
- David C. Morse (ORCID: https://orcid.org/0000-0002-1033-8641)
- M. W. Matsen (ORCID: https://orcid.org/0000-0003-2099-0892)
Institutions
- University of Minnesota (US)
- University of Waterloo (CA)
- Ulsan National Institute of Science and Technology (KR)
Publication Details
- Journal
- Macromolecules
- Published
- 2024-10-07
- DOI
- https://doi.org/10.1021/acs.macromol.4c01617
- Citations
- 2
- Primary Topic
- Block Copolymer Self-Assembly
- Type
- article
- Field-Weighted Citation Impact
- 0.23
Funders
- National Research Foundation of Korea
- Alliance de recherche numérique du Canada
- Natural Sciences and Engineering Research Council of Canada
- Office of Advanced Cyberinfrastructure