Low-voltage and high-contrast polymer dispersed liquid crystals enabled by ferroelectric fluoro-copolymer doped polyimide film

• Ferro-PI film is composed of P(VDF-TrFE) copolymer and homogeneous polyimide. • PDLCs are sandwiched between the Ferro-PI films. • Ferro-PI films increase the effective voltage drop across the PDLCs. • Ferro-PI films promise PDLCs with a low voltage, high contrast, and wide view angle. Smart windows incorporating polymer dispersed liquid crystal (PDLC) technology provide user-friendly operation and play a significant role in intelligent buildings and building energy conservation. Long standing issues of the PDLCs such as high driving voltage, low contrast ratio, and narrow viewing angle hinder their applications. Here PDLCs are sandwiched between the hybrid substrates composed of the ferroelectric polyvinylidene fluoride trifluoroethylene (P(VDF-TrFE)) copolymer and the homogeneous polyimide. The high dielectric constant and ion-trapping ability of ferroelectric copolymers increase the effective voltage drop in the PDLCs. Concurrently, the local electric field created by large dipole moment of ferroelectric copolymers triggers the alignment of liquid crystals (LCs) along the applied field. These synergistic effects contribute to a substantial decrease in the driving voltage of PDLCs. In the opaque state, the random dipole moments in ferroelectric copolymers disrupt the LC orientations near hybrid substrates, thereby increasing the light scattering and reducing the transmission of PDLCs. Consequently, the proposed PDLCs exhibit a contrast ratio ∼2× higher compared to the conventional PDLCs at normal incident. Moreover, the proposed PDLCs demonstrate a wider viewing angle in the transparent state compared to conventional PDLCs. This development promises energy-efficient, eco-friendly, and cost-effective smart windows.