Crack tip stress intensification in strain-induced crystallized elastomer

• We revealed the stress field near a crack tip of strain-induced crystalized elastomers. • We computed the crack tip stress field from the micro-scale DIC deformation field data. • We derived a strain energy function replicating the stress-strain data in five deformation types. • Crystallization causes a significant stress increase and strain decrease near a crack tip. Natural rubber (NR) exhibits strain-induced crystallization (SIC), enhancing tearing strength and crack resistance. However, the reinforcement mechanism along with nonuniform strain around a crack tip remains unclear. We reveal the nonuniform stress field around a crack tip using the DIC-based deformation field data and a hyperelasticity approach. A hyperelastic strain energy density function ( W ) is derived to be able to replicate stress-strain data across various deformations, encompassing equal and unequal biaxial, uniaxial, and pure shear stretching. These data cover the full range and magnitude of deformations around the crack tip. SIC significantly impacts the singular behaviors of strain and stress near the crack tip, causing a pronounced stress increase and strain decrease within the SIC zone that extends up to approximately 100 μm away from the crack tip. This results in a distinct crossover in singularity power-law index between the SIC zone and the fully amorphous zone. With increasing crack opening, the stress upturn intensifies, and the crossover shifts away from the crack tip due to SIC zone enlargement and local crystallinity increase. These findings deepen our understanding of the physics of SIC near crack tips and its reinforcement mechanism in strain-induced crystallizable soft solid materials.