Fluorotelomer alcohol (FTOH) emission rates from new and old rain jackets to air determined by iodide high-resolution chemical ionization mass spectrometry

Per- and polyfluoroalkyl substances (PFAS), which include fluorotelomer alcohols (FTOHs), are synthetic chemicals used in consumer products because of their water-, stain-, and grease-repellent properties; thus, PFAS are commonly found in functional clothing such as rain jackets. To date, emissions of PFAS from products to indoor air have not been well characterized, although many PFAS-containing products are used and stored indoors. We used a test chamber connected to a high-resolution time-of-flight chemical ionization mass spectrometer equipped with iodide as a reagent ion (I-HR-ToF-CIMS) to measure emission rates for four FTOHs from 10 rain jackets and one backpack cover. The materials were categorized as old/used, new, or “PFAS-free”, and they were tested under two different scenarios, i.e., immediately out of package and after airing out. We observed real-time FTOH emissions from all materials. Under the out-of-package scenario, emissions of 6:2, 8:2 and 10:2 FTOH showed characteristics that indicate mass transfer is limited by internal diffusion, with a high initial peak followed by a lower steady-state emission rate. Peak emission rates correlated well with material-phase concentrations determined by an offline extractive gas chromatography-mass spectrometry (GC-MS) method. Our results further suggest that the old, used jackets had, on average, higher peak emission rates and higher material-phase concentrations than the new jackets, largely driven by 8:2 FTOH. “PFAS-free” materials had the overall lowest emission rates and material-phase concentrations. After airing out, emission rates were on average an order of magnitude lower than peak emission rates. Our findings emphasize the importance of considering consumer products like rain jackets as sources of indoor exposure to PFAS. Fluorotelomer alcohol emissions from new and old rain jackets were measured by real-time high resolution chemical ionization mass spectrometry. High peak and lower steady state emission rates suggest that mass transfer was limited by internal diffusion. • Real-time I-HR-ToF-CIMS measurements of FTOH emission rates are reported. • Materials included 10 rain jackets and one backpack cover. • 6:2 FTOH, 8:2 FTOH and 10:2 FTOH exhibit VOC-like emission behavior. • Peak emission rates correlated with FTOH material concentrations measured by GC-MS. • Despite a small sample size, emissions were on average higher for old, used rain jackets.