Fluorescent Ionic Liquid Aggregates: A Self-Assembled Approach for Pesticide Detection and Catalysis

The unregulated use of pesticides, industrial discharge of heavy metals, waste, and agricultural runoff may contaminate surface water and groundwater, consequently threatening ecosystems and human health. Thus, the sensitive detection and degradation of pesticides are essential for safety. In this context, herein, we have developed benzimidazolium-based fluorescent surfactant assemblies <b>TA-1/SDS</b> and <b>TA-2/SDBS</b>, which exhibit aggregation-induced emission enhancement in an aqueous medium. The aggregates (<b>TA-1/SDS</b> and <b>TA-2/SDBS</b>) displayed a turn-on emission response upon interaction with carbendazim and azamethiphos with limits of detection 7.5 and 7.8 nM, respectively. The FE-SEM and AFM studies revealed that <b>TA-1/SDS</b> and <b>TA-2/SDBS</b> undergo self-assembly with the addition of AZA and CBZ, resulting in the formation of dendritic structures. In addition to the quantification of AZA and CBZ, <b>TA-1/SDS</b> and <b>TA-2/SDBS</b> have also been evaluated to degrade both pesticides and validated using ³¹P NMR spectroscopy and LC-MS spectrometry.