Free‐electron coupling to surface polaritons mediated by small scatterers

The ability of surface polaritons (SPs) to enhance and manipulate light fields down to deep-subwavelength length scales enables applications in optical sensing and nonlinear optics at the nanoscale. However, the wavelength mismatch between light and SPs prevents direct optical excitation of surface-bound modes, thereby limiting the widespread development of SP-based photonics. Free electrons are a natural choice to directly excite strongly confined SPs because they can supply field components of high momentum at designated positions with subnanometer precision. Here, we theoretically explore free-electron-SP coupling mediated by small scatterers and show that low-energy electrons can efficiently excite surface modes with a maximum probability reached at an optimum surface-scatterer distance. By aligning the electron beam with a periodic array of scatterers placed near a polariton-supporting interface, in-plane Smith-Purcell emission results in the excitation of surface modes along well-defined directions. Our results support using scattering elements to excite SPs with low-energy electrons.