Copper(II) triflate-mediated addition reaction of 2-tributylstannyl-1,3-dithiane with imines

Abstract The addition of 2-tributylstannyl-1,3-dithiane to imines was achieved using copper(II) triflate in MeNO2 at room temperature. Furthermore, this reaction can be applied to various aromatic and heteroaromatic imines. Consequently, the corresponding α-amino-1,3-dithiane derivatives were efficiently and readily synthesized under mild conditions.

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Publication Details

Journal
Chemistry Letters
Published
2024-10-01
DOI
https://doi.org/10.1093/chemle/upae182
Primary Topic
Synthesis and Catalytic Reactions
Type
article
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article

Copper(II) triflate-mediated addition reaction of 2-tributylstannyl-1,3-dithiane with imines

Hirotaka Kagoshima, Junki Kawamoto, Yuki Takeo, Yuta Narui et al.
Chemistry Letters
Synthesis and Catalytic Reactions
article

Copper(II) triflate-mediated addition reaction of 2-tributylstannyl-1,3-dithiane with imines

Hirotaka Kagoshima, Junki Kawamoto, Yuki Takeo, Yuta Narui, Shiori Ohkubo, T. KAWAI
article en

Abstract

Abstract The addition of 2-tributylstannyl-1,3-dithiane to imines was achieved using copper(II) triflate in MeNO2 at room temperature. Furthermore, this reaction can be applied to various aromatic and heteroaromatic imines. Consequently, the corresponding α-amino-1,3-dithiane derivatives were efficiently and readily synthesized under mild conditions.

Chemistry LettersVol. 53(10)
Ibaraki University (JP)
Clean water and sanitation
Openalex Percentile: Top 87%
Synthesis and Catalytic Reactions
DOISourceOpenAlex
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Copper(II) triflate-mediated addition reaction of 2-tributylstannyl-1,3-dithiane with imines — Hirotaka Kagoshima, Junki Kawamoto, et al. · Chemistry Letters (2024) | TGRS Research Map | TGRS