Visual colorimetric label for real-time monitoring of SO2 concentration change in grape and mango during storage

Sulfur dioxide (SO₂) is widely utilized as a preservative in food transportation and storage, but excessive consumption poses health risks. This study presents a novel and efficient method for the real-time detection of SO₂ using a sensor named TK, synthesized from triphenylamine and 2-cyanomethyl-1-methyl-quinolinium. The core mechanism involves the Michael addition reaction of the CC bond in TK with SO₂, which disrupts the intramolecular charge transfer process, resulting in a significant color change and a blue shift in fluorescence emission. Methodologically, the sensor's response was quantified by the change in fluorescence intensity ratio (I₄₂₅/I₆₄₇) within a SO₂ concentration range of 0-180 μM. The sensor exhibited high sensitivity and selectivity. For practical application, TK was incorporated into hydrophilic polyvinyl alcohol to create a smart label capable of visual colorimetry and fluorescence analysis. SO₂ concentration changes were monitored by using this label, demonstrated by the color transition from burgundy red to colorless, yielding a maximum color difference (ΔE) of 73.6. The smart label was successfully used to monitor the quality of various grapes and mangoes during long-term storage, providing a reliable, equipment-independent method suitable for household use. The study offers a new tool for enhancing food safety and mitigating health risks associated with SO₂ exposure.