Organometallic Iridium-Complex-Functionalized Nanographene Catalysts for Low-Temperature Hydrogenation of Carbonyl Derivatives
An organometallic iridium (Ir)-complex-functionalized nanographene catalyst <b>Ir-PyPh-GC</b> was prepared via a two-step strategy involving amide ligand modification and metal Ir coordination. <b>Ir-PyPh-GC</b> showed ultrahigh hydrogenation capability, good recyclability, and selectivity for carbonyl derivatives (ketones, aldehydes, and quinones) at a low temperature (40 °C). The as-prepared Ir-complex-based catalyst is less expensive, making it feasible for industrial application.
Authors
- Lijun Zhao (ORCID: https://orcid.org/0000-0001-9664-8853)
- Xun Sun (ORCID: https://orcid.org/0000-0002-4316-2988)
- Libo Sun (ORCID: https://orcid.org/0000-0002-5006-8455)
- Caixia Qi (ORCID: https://orcid.org/0000-0003-1590-4064)
- Hangyu Zhou (ORCID: https://orcid.org/0000-0002-0806-811X)
- Qing Zhou (ORCID: https://orcid.org/0000-0002-9262-1810)
- Peng Xiao (ORCID: https://orcid.org/0000-0001-5606-9806)
- Shixin Zhang
- Yue Zhao
- Huijuan Su
- Ke Yang (ORCID: https://orcid.org/0009-0009-2159-4980)
Institutions
- Yantai University (CN)
- Shanghai Electric (China) (CN)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2024-10-03
- DOI
- https://doi.org/10.1021/acs.inorgchem.4c03602
- Citations
- 1
- Primary Topic
- Asymmetric Hydrogenation and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.16
Funders
- National Natural Science Foundation of China
- Natural Science Foundation of Shandong Province
- Government of Shandong Province