Electric dipole polarizabilities and tune-out wavelengths for 23<i>S</i>1 and 33<i>S</i>1 states of Be2+

The electric dipole polarizabilities and the tune-out wavelengths for the n3S1 (n = 2, 3) states of Be2+ are determined through the application of the relativistic full-configuration-interaction approach. Our calculations directly integrate the mass shift operator into the Dirac-Coulomb-Breit Hamiltonian and further assess the quantum electrodynamics (QED) correction to the dynamic dipole polarizabilities using perturbation theory. The results reveal that the static electric dipole polarizability of the 23S1 and 33S1 states, as well as the 93 nm tune-out wavelength of the 23S1 state and the 238 nm tune-out wavelength of the 33S1 state, exhibits a high sensitivity to QED correction, which exceeds 80 ppm, providing a sensitive test for atomic structure theory.

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Publication Details

Journal
The Journal of Chemical Physics
Published
2024-10-02
DOI
https://doi.org/10.1063/5.0229060
Primary Topic
Cold Atom Physics and Bose-Einstein Condensates
Type
article
Field-Weighted Citation Impact
0.00

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article

Electric dipole polarizabilities and tune-out wavelengths for 23S1 and 33S1 states of Be2+

Xiao-Qiu Qi, Fang-Fei Wu, Aixi Chen
The Journal of Chemical Physics
Cold Atom Physics and Bose-Einstein Condensates
article

Electric dipole polarizabilities and tune-out wavelengths for 23S1 and 33S1 states of Be2+

Xiao-Qiu Qi, Fang-Fei Wu, Aixi Chen
article en

Abstract

The electric dipole polarizabilities and the tune-out wavelengths for the n3S1 (n = 2, 3) states of Be2+ are determined through the application of the relativistic full-configuration-interaction approach. Our calculations directly integrate the mass shift operator into the Dirac-Coulomb-Breit Hamiltonian and further assess the quantum electrodynamics (QED) correction to the dynamic dipole polarizabilities using perturbation theory. The results reveal that the static electric dipole polarizability of the 23S1 and 33S1 states, as well as the 93 nm tune-out wavelength of the 23S1 state and the 238 nm tune-out wavelength of the 33S1 state, exhibits a high sensitivity to QED correction, which exceeds 80 ppm, providing a sensitive test for atomic structure theory.

The Journal of Chemical PhysicsVol. 161(13)
Zhejiang Sci-Tech University (CN), China Jiliang University (CN)
National Natural Science Foundation of China
Openalex Percentile: Top 85%
Cold Atom Physics and Bose-Einstein Condensates
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