Satellite-observed relationships between land cover, burned area, and atmospheric composition over the southern Amazon

Abstract. Land surface changes can have substantial impacts on biosphere–atmosphere interactions. In South America, rainforests abundantly emit biogenic volatile organic compounds (BVOCs), which, when coupled with pyrogenic emissions from deforestation fires, can have substantial impacts on regional air quality. We use novel and long-term satellite records of five trace gases, namely isoprene (C5H8), formaldehyde (HCHO), methanol (CH3OH), carbon monoxide (CO), and nitrogen dioxide (NO2), in addition to aerosol optical depth (AOD), vegetation (land cover and leaf area index), and burned area. We characterise the impacts of biogenic and pyrogenic emissions on atmospheric composition for the period 2001 to 2019 in the southern Amazon, a region of substantial deforestation. The seasonal cycle for all of the atmospheric constituents peaks in the dry season (August–October), and the year-to-year variability in CO, HCHO, NO2, and AOD is strongly linked to the burned area. We find a robust relationship between the broadleaf forest cover and total column C5H8 (R2 = 0.59), while the burned area exhibits an approximate fifth root power law relationship with tropospheric column NO2 (R2 = 0.32) in the dry season. Vegetation and burned area together show a relationship with HCHO (R2 = 0.23). Wet-season AOD and CO follow the forest cover distribution. The land surface variables are very weakly correlated with CH3OH, suggesting that other factors drive its spatial distribution. Overall, we provide a detailed observational quantification of biospheric process influences on southern Amazon regional atmospheric composition, which in future studies can be used to help constrain the underpinning processes in Earth system models.