Density Differences’ Effect on Phase Transition Kinetics

In this theoretical study, we investigate the impact of density differences between the growing new phase and the parent phase on the overall transformation degree. By extending Kolmogorov's formalism, we derive an expression for the overall volume transformation degree, which becomes relevant when density differences are not negligible. We demonstrate that the volume and mass transformation degrees differ in the presence of density differences and provide an expression for the mass transformation degree.

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Publication Details

Journal
The Journal of Physical Chemistry B
Published
2024-10-02
DOI
https://doi.org/10.1021/acs.jpcb.4c04898
Primary Topic
Polymer crystallization and properties
Type
article
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article

Density Differences’ Effect on Phase Transition Kinetics

K. Avramova, Alexander Karamanov
The Journal of Physical Chemistry B
Polymer crystallization and properties
article

Density Differences’ Effect on Phase Transition Kinetics

K. Avramova, Alexander Karamanov
article en

Abstract

In this theoretical study, we investigate the impact of density differences between the growing new phase and the parent phase on the overall transformation degree. By extending Kolmogorov's formalism, we derive an expression for the overall volume transformation degree, which becomes relevant when density differences are not negligible. We demonstrate that the volume and mass transformation degrees differ in the presence of density differences and provide an expression for the mass transformation degree.

The Journal of Physical Chemistry BVol. 128(50)
Bulgarian Academy of Sciences (BG), Institute of Physical Chemistry (BG)
Climate action
Openalex Percentile: Top 87%
Polymer crystallization and properties
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