Unifying methods for optimal control in non-Markovian quantum systems via process tensors

The large dimensionality of environments is the limiting factor in applying optimal control to open quantum systems beyond the Markovian approximation. Various methods exist to simulate non-Markovian systems, which effectively reduce the environment to a number of active degrees of freedom. Here, we show that several of these methods can be expressed in terms of a process tensor in the form of a matrix-product-operator, which serves as a unifying framework to show how they can be used in optimal control and to compare their performance. The matrix-product-operator form provides a general scheme for computing gradients using back propagation and allows the efficiency of the different methods to be compared via the bond dimensions of their respective process tensors.

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Publication Details

Journal
The Journal of Chemical Physics
Published
2024-09-28
DOI
https://doi.org/10.1063/5.0226031
Citations
4
Primary Topic
Spectroscopy and Quantum Chemical Studies
Type
article
Field-Weighted Citation Impact
1.35

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article

Unifying methods for optimal control in non-Markovian quantum systems via process tensors

P. R. Eastham, Carlos Ortega-Taberner, Gerald E. Fux, Eoin P. Butler et al.
4 citations
The Journal of Chemical Physics
Spectroscopy and Quantum Chemical Studies
1.35
article

Unifying methods for optimal control in non-Markovian quantum systems via process tensors

P. R. Eastham, Carlos Ortega-Taberner, Gerald E. Fux, Eoin P. Butler, Eoin O’Neill
article en
4 citations

Abstract

The large dimensionality of environments is the limiting factor in applying optimal control to open quantum systems beyond the Markovian approximation. Various methods exist to simulate non-Markovian systems, which effectively reduce the environment to a number of active degrees of freedom. Here, we show that several of these methods can be expressed in terms of a process tensor in the form of a matrix-product-operator, which serves as a unifying framework to show how they can be used in optimal control and to compare their performance. The matrix-product-operator form provides a general scheme for computing gradients using back propagation and allows the efficiency of the different methods to be compared via the bond dimensions of their respective process tensors.

The Journal of Chemical PhysicsVol. 161(12)
The Abdus Salam International Centre for Theoretical Physics (ICTP) (IT), Trinity College Dublin (IE), Center for Theoretical Physics (PL)
Science Foundation Ireland
Peace, Justice and strong institutions
Openalex Percentile: Top 20%
Spectroscopy and Quantum Chemical Studies
1.35
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