Gas extraction generation of gas mixtures of polar organic compounds at trace concentration levels

The patterns of generating gas mixtures of polar organic compounds at the level of their MAC (several µg/m³) were studied using the method of continuous gas extraction from aqueous solutions with a known concentration in combination with dilution by a stream of diluent gas. The necessary distribution coefficients of phenol, isomeric cresols, nitrobenzene, and alkanols С4–С6 between the aqueous and gas phases (nitrogen) were determined. A two-stage generation scheme is proposed, based on saturating the sorbent (activated carbon) with a flow of extraction gas containing the target components at a specified concentration, followed by desorption by a flow of pure extraction gas.

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Publication Details

Journal
Журнал аналитической химии
Published
2024-09-30
DOI
https://doi.org/10.31857/s0044450224040042
Primary Topic
Chemical Thermodynamics and Molecular Structure
Type
article
Field-Weighted Citation Impact
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article

Gas extraction generation of gas mixtures of polar organic compounds at trace concentration levels

Valeriy Spivakovsky, E. A. Znamenskaya, A. A. Zheludovskaya, M. E. Grega et al.
Журнал аналитической химии
Chemical Thermodynamics and Molecular Structure
article

Gas extraction generation of gas mixtures of polar organic compounds at trace concentration levels

Valeriy Spivakovsky, E. A. Znamenskaya, A. A. Zheludovskaya, M. E. Grega, O. V. Rodinkova
article en

Abstract

The patterns of generating gas mixtures of polar organic compounds at the level of their MAC (several µg/m³) were studied using the method of continuous gas extraction from aqueous solutions with a known concentration in combination with dilution by a stream of diluent gas. The necessary distribution coefficients of phenol, isomeric cresols, nitrobenzene, and alkanols С4–С6 between the aqueous and gas phases (nitrogen) were determined. A two-stage generation scheme is proposed, based on saturating the sorbent (activated carbon) with a flow of extraction gas containing the target components at a specified concentration, followed by desorption by a flow of pure extraction gas.

Журнал аналитической химииVol. 79(4)
St Petersburg University (RU)
Openalex Percentile: Top 88%
Chemical Thermodynamics and Molecular Structure
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