Effects of geometric isomerism in electron ionization mass spectra of dialkyl 1,4‐cyclohexanedicarboxylates
The possibility of the unambiguous identification of stereoisomeric dialkyl cis and trans 1,4-cyclohexanedicarboxylates on the basis of their EI mass spectra was shown. The differences in mass spectra of the isomers are due to the conformational rigidity of the considered monocyclic molecules, which ensures the unique stereoselectivity of the elimination of neutral molecules owing to the 1,3-cis-diaxial proximity effect.
Authors
- M. E. Zimens (ORCID: https://orcid.org/0000-0003-3589-7199)
- Р. С. Борисов (ORCID: https://orcid.org/0000-0002-8203-7055)
- K. A. Kadirbekov (ORCID: https://orcid.org/0000-0003-3141-7661)
- В. Г. Заикин (ORCID: https://orcid.org/0000-0001-9360-8442)
- Yersin A. Tussupkaliyev
- Umirzak Zh. Jussipbekov
Institutions
- Russian Academy of Sciences (RU)
- D. Mendeleyev University of Chemical Technology of Russia (RU)
- A.V. Topchiev Institute of Petrochemical Synthesis (RU)
Publication Details
- Journal
- Rapid Communications in Mass Spectrometry
- Published
- 2024-09-26
- DOI
- https://doi.org/10.1002/rcm.9915
- Primary Topic
- Mass Spectrometry Techniques and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00