A Thermodynamic Analysis of a Proton Exchange Membrane Electrolyzer

A thermodynamic, first law analysis was conducted to understand the temperature of a proton exchange membrane electrolyzer when operated at a constant voltage and feed water flow rate. When using the electrolyzer voltage, current, liquid water feed rate and temperature, the electrolyzer operating temperature can be calculated. Heat losses can also be accounted for but are currently neglected. Carpet plots show the resulting electrolyzer temperature under varying conditions. The calculated temperatures are in very good agreement with measurements conducted in our laboratories.