Integral fractionation of Arundo donax using biphasic mixtures of solvents derived from biomass: An environmentally friendly approach

Arundo donax , one of the most invasive plants in the world, but also a promising source of lignocellulose materials was employed as a feedstock for a biorefinery process. Water-extracted Arundo donax samples were subjected to one-step biphasic fractionation in catalyzed media containing water and 1-butanol, an environmentally-friendly solvent. The effects of selected operational variables (catalyst concentration, temperature and reaction time) on the measured effects (solid recovery yield and compositions of the solid, aqueous and organic phases resulting from treatments) were assessed using statistical methods. The results allowed a quantitative discussion on aspects regarding the selectivity of component separation (lignin, glucan, and hemicelluloses), the overall recovery of valuable products, and the selection of operational conditions enabling extensive delignification (around to 90 %) and high recovery rates of glucan and hemicellulose-derived sugars (above 80 % and 75 %, respectively). This study provides new insights into biphasic fractionation, highlighting the selective separation of hemicellulose, cellulose and lignin into a single and sustainable process, thereby by enhancing biomass resource while reducing environmental impact. • New insight into biphasic systems for the selective separation of AD constituents. • Single process for the efficient separation of hemicellulose, cellulose and lignin. • Extensive delignification and high recovery rates of glucan and hemicellulose. • Aqueous phase with high concentration xylose as mono- or oligosaccharide. • Lignin of high purity and highly reactive for further valorization.