General Inverse Problem Solution for Two-Level Systems and Its Application to Charge Transfer

Two-level quantum systems are building blocks of quantum technologies, where the qubit is the basic unit of quantum information. The ability to design driving fields that produce prespecified evolutions of relevant physical observables is crucial to the development of such technologies. Using vector algebra and recently developed strategies for generating solvable two-level Hamiltonians, we construct the general solution to the inverse problem for a spin in a time-dependent magnetic field and its extension to any two-level system associated with fictitious spin and field. We provide a general expression for the field that drives the dynamics of the system so as to realize prescribed time evolutions of the expectation values of the Pauli operators and the autocorrelation of the Pauli vector. The analysis is applied to two-state charge transfer systems, showing that the charge transfer process can be seen as a motion of the state of the associated fictitious qubit on the Bloch sphere, and that the expectation values of the related Pauli operators describe the interference between the two differently localized electronic states and their population difference. Our formulation is proposed as a basic step towards potential uses of charge transfer in quantum computing and quantum information transfer.