A Negatively Curved Nanographene with Four Embedded Heptagons
Negatively curved nanographenes are considered as cutouts of three-dimensional fully sp<sup>2</sup>-hybridized carbon allotropes such as Schwarzites. Here we present the synthesis of a C<sub>76</sub> cut-out of the Schwarzite 8-4-1-p proposed by Lenosky et al. and investigate its optical as well as electrochemical properties. Furthermore, supramolecular interactions with fullerenes C<sub>60</sub> and C<sub>70</sub> were studied.
Authors
- Tobias Kirschbaum
- Michael Mastalerz (ORCID: https://orcid.org/0000-0003-3231-4816)
- Sven M. Elbert (ORCID: https://orcid.org/0009-0004-5392-0609)
- Moritz P. Schuldt
- Frank Röminger
- Laura Weber
- Owen T. A. Paine
Institutions
- Heidelberg University (DE)
Publication Details
- Journal
- Journal of the American Chemical Society
- Published
- 2024-09-27
- DOI
- https://doi.org/10.1021/jacs.4c09185
- Citations
- 34
- Primary Topic
- Synthesis and Properties of Aromatic Compounds
- Type
- article
- Field-Weighted Citation Impact
- 8.50
Funders
- Deutsche Forschungsgemeinschaft