Carbene-Catalyzed [3 + 3] Annulation of Enals and Vinyl Sulfoxonium Ylides
Carbene-catalyzed [3 + 3] annulation of enals and vinyl sulfoxonium ylides has been demonstrated. This method efficiently synthesizes a range of 2-sulfenylidene-3-cyclohexen-1-ones with high atom economy. Notably, the presence of the sulfoxonium ylide moiety in the obtained products significantly enhances their potential for further synthetic transformations.
Authors
- Zhenqian Fu (ORCID: https://orcid.org/0000-0002-3806-6684)
- Hailong Zhang (ORCID: https://orcid.org/0000-0001-6559-3917)
- Haibin Zhu (ORCID: https://orcid.org/0009-0002-1578-5587)
- Jinhua Liu (ORCID: https://orcid.org/0000-0002-4031-3031)
- Xiaoxiang Zhang (ORCID: https://orcid.org/0000-0001-9811-0221)
- Dongping Shi (ORCID: https://orcid.org/0000-0002-2803-358X)
- Weiqi Yang
- Siru Feng
Institutions
- Nanjing Tech University (CN)
- Nanjing Forestry University (CN)
Publication Details
- Journal
- The Journal of Organic Chemistry
- Published
- 2024-09-26
- DOI
- https://doi.org/10.1021/acs.joc.4c01587
- Citations
- 1
- Primary Topic
- Cyclopropane Reaction Mechanisms
- Type
- article
- Field-Weighted Citation Impact
- 0.25
Funders
- National Natural Science Foundation of China
- Natural Science Foundation of Jiangsu Province