Phenylseleno trifluoromethoxylation of alkenes
Trifluoromethoxylated molecules and selenylated compounds find a wide range of interesting applications, but separately. In order to combine the potential of these two motifs and to propose a new class of compounds, we have developed an electrophilic phenylseleno trifluoromethoxylation of alkenes, which leads to β-selenylated trifluoromethoxylated compounds or, upon subsequent reduction, to the trifluoromethoxylated ones.
Authors
- Thierry Billard (ORCID: https://orcid.org/0000-0002-2937-9523)
- Gilles Hanquet (ORCID: https://orcid.org/0000-0001-8829-1225)
- Fabien Toulgoat (ORCID: https://orcid.org/0000-0001-7339-4985)
- Frédéric R. Leroux (ORCID: https://orcid.org/0000-0001-8900-5753)
- Clément Delobel (ORCID: https://orcid.org/0009-0007-8447-1748)
- Armen Panossian (ORCID: https://orcid.org/0000-0003-2317-1200)
Institutions
- Université Claude Bernard Lyon 1 (FR)
- Centre National de la Recherche Scientifique (FR)
- École d'Ingénieurs en Chimie et Sciences du Numérique (FR)
- Université de Strasbourg (FR)
Publication Details
- Journal
- Beilstein Journal of Organic Chemistry
- Published
- 2024-09-26
- DOI
- https://doi.org/10.3762/bjoc.20.207
- Citations
- 2
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.42
Funders
- Agence Nationale de la Recherche
- Centre National de la Recherche Scientifique