First Example of Aryl–Hetaryl Cross-Coupling via [5,5]-Sigmatropic Rearrangement
Abstract Polysubstituted furans and thiophenes with orthogonal functional groups were synthesized by a Strecker-type reaction leading to (arylaminonitriles), which underwent a [5,5]-sigmatropic rearrangement under mild conditions. The intramolecular character of the rearrangement was additionally proved.
Authors
- Валентин А. Чебанов (ORCID: https://orcid.org/0000-0001-7564-778X)
- Svitlana V. Shishkina (ORCID: https://orcid.org/0000-0002-3946-1061)
- Oleksandr V. Buravov (ORCID: https://orcid.org/0009-0008-8433-5524)
- Victor O. Tomak
Institutions
- National Academy of Sciences of Ukraine (UA)
- State Scientific Institution “Institute for Single Crystals” of National Academy of Sciences of Ukraine (UA)
- Institute of Organic Chemistry (UA)
- Enamine (Ukraine) (UA)
- V. N. Karazin Kharkiv National University (UA)
Publication Details
- Journal
- Synthesis
- Published
- 2024-09-26
- DOI
- https://doi.org/10.1055/s-0043-1775403
- Primary Topic
- Catalytic C–H Functionalization Methods
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Academy of Sciences of Ukraine