The Influence of Grain Size on Microstructure Evolution in CeO2 under Xenon Ion Irradiation

Large-grained UO₂ is considered a potential accident-tolerant fuel (ATF) due to its superior fission gas retention capabilities. Irradiation experiments for cerium dioxide (CeO₂), used as a surrogate fuel, is a common approach for evaluating the performance of UO₂. In this work, spark plasma sintered CeO₂ pellets with varying grain sizes (145 nm, 353 nm, and 101 μm) and a relative density greater than 93.83% were irradiated with 4 MeV Xe ions at a fluence of 2 × 10¹⁵ ions/cm² at room temperature, followed by annealing at 600 °C for 3 h. Microstructure, including dislocation loops and bubble morphology of the irradiated samples, has been characterized. The average size of dislocation loops increases with increasing grain size. Large-sized dislocation loops are absent near the grain boundary because the boundary absorbs surrounding defects and prevents the dislocation loops from coalescing and expanding. The distribution of bubbles within the grain is uniform, whereas the large-sized and irregularly shaped xenon bubbles observed in the small grain exhibit pipe diffusion along the grain boundaries. The bubble diameter in the large-grained pellet is the smallest. As the grain size increases, the volumetric swelling of the irradiated pellets decreases while the areal density of Xe bubbles increases. Elemental segregation, which tends to occur at dislocation loops and grain boundaries, has been analyzed. Large-grained CeO₂ pellet with lower-density grain boundaries exhibits better resistance to volumetric swelling and elemental segregation, suggesting that large-grained UO₂ pellets could serve as a potential ATF.