Numerical and Experimental Study on the Performance of Photovoltaic—Trombe Wall in Hot Summer and Warm Winter Regions: Energy Efficiency Matching and Application Potential

Enhancing the energy efficiency of building envelopes is one of the key strategies for energy conservation and reducing consumption in buildings. This study employs numerical research methods to explore the impact of crucial factors such as solar cell coverage, air channel height, indoor relative humidity, and indoor wind speed on the power generation performance and thermal comfort of a photovoltaic (PV)—Trombe wall. The dynamic changes in optical and thermal performance and energy efficiency matching mechanisms of this system are also discussed in hot summer and warm winter regions. The research findings indicate that the periods of good thermal comfort and power generation efficiency for humans are from 9:00 to 17:00 in winter. In summer, these periods are from 5:00 to 8:00 as well as from 17:00 to 20:00. When the system height is 2 m, the electricity price for power supplied by the PV—Trombe wall system is 25% lower than the residential price, with an annual energy generation of 322.5 kWh/m2 of solar panel, which can save USD 6.35 in costs. Moreover, an experiment is conducted to investigate the thermoelectric correlation by constructing a traditional Trombe wall and an external PV—Trombe wall. When the coverage reached 52.08%, the overall system efficiency was maximized. At a coverage of 78.12%, the system’s thermal efficiency was at its lowest, while the maximum power generation was 510.3 W. It can be seen that the PV—Trombe wall possesses good economic benefits and energy saving as well as emission reduction potential in hot summers and warm winters regions, and the smooth implementation of related works will effectively promote its applications and promotions.