Asymmetrization of the Indacene Core in the Molecules of Monobromine-Containing BODIPY Derivatives: Experiment and Theory

The molecular structures and crystal packings of three new BODIPY compounds with a bromine atom in the α-, β-, and γ-position were analyzed. The asymmetrization of the central conjugated fragment was demonstrated for the first time, with its expression and localization determined by the position of the substituent relative to the borofluoride core of the molecule.

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Učënye zapiski Kazanskogo universiteta. Seriâ Estestvennye nauki/Učënye zapiski Kazanskogo universiteta. Seriâ Estestvennye nauki/Učenye zapiski Kazanskogo gosudarstvennogo universiteta. Seriâ Estestvennye nauki
Published
2024-09-21
DOI
https://doi.org/10.26907/2542-064x.2024.3.373-386
Primary Topic
Luminescence and Fluorescent Materials
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article
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article

Asymmetrization of the Indacene Core in the Molecules of Monobromine-Containing BODIPY Derivatives: Experiment and Theory

О.А. Lodochnikova, L. V. Frantsuzova, D. P. Gerasimova
Učënye zapiski Kazanskogo universiteta. Seriâ Estestvennye nauki/Učënye zapiski Kazanskogo universiteta. Seriâ Estestvennye nauki/Učenye zapiski Kazanskogo gosudarstvennogo universiteta. Seriâ Estestvennye nauki
Luminescence and Fluorescent Materials
article

Asymmetrization of the Indacene Core in the Molecules of Monobromine-Containing BODIPY Derivatives: Experiment and Theory

О.А. Lodochnikova, L. V. Frantsuzova, D. P. Gerasimova
article en

Abstract

The molecular structures and crystal packings of three new BODIPY compounds with a bromine atom in the α-, β-, and γ-position were analyzed. The asymmetrization of the central conjugated fragment was demonstrated for the first time, with its expression and localization determined by the position of the substituent relative to the borofluoride core of the molecule.

Učënye zapiski Kazanskogo universiteta. Seriâ Estestvennye nauki/Učënye zapiski Kazanskogo universiteta. Seriâ Estestvennye nauki/Učenye zapiski Kazanskogo gosudarstvennogo universiteta. Seriâ Estestvennye naukiVol. 166(3)
Kazan Federal University (RU), A.E. Arbuzov Institute of Organic and Physical Chemistry (RU)
Kazan Federal University, Russian Academy of Sciences
Zero hunger
Openalex Percentile: Top 90%
Luminescence and Fluorescent Materials
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Asymmetrization of the Indacene Core in the Molecules of Monobromine-Containing BODIPY Derivatives: Experiment and Theory — О.А. Lodochnikova, L. V. Frantsuzova, et al. · Učënye zapiski Kazanskogo universiteta. Seriâ Estestvennye nauki/Učënye zapiski Kazanskogo universiteta. Seriâ Estestvennye nauki/Učenye zapiski Kazanskogo gosudarstvennogo universiteta. Seriâ Estestvennye nauki (2024) | TGRS Research Map | TGRS