Strategies and Tactics for Site Specific Deuterium Incorporation at Each Available Carbon Atom of α-Pinene
The development of several unique strategies and tactics for the synthesis of α-pinene isotopologues that has culminated in access to all eight possible isomers with deuterium incorporated selectively at each available carbon atom is described. Access to this library of isotopologues provides new tools to more fully investigate the atmospheric autoxidation of α-pinene, a complex process that plays a major role in the formation of secondary organic aerosol in the Earth's atmosphere.
Authors
- Nicolle A. Doering (ORCID: https://orcid.org/0000-0001-5191-2120)
- Zhouyang Ren (ORCID: https://orcid.org/0009-0002-5335-1034)
- Marvin Vega
- Richmond Sarpong
- Franz M. Geiger (ORCID: https://orcid.org/0000-0001-8569-4045)
- Jonathan Varelas
- Regan J. Thomson (ORCID: https://orcid.org/0000-0001-5546-4038)
- Jingyi Luo (ORCID: https://orcid.org/0000-0003-2988-1465)
- Mary Alice Upshur
Institutions
- Northwestern University (US)
- University of California, Berkeley (US)
Publication Details
- Journal
- The Journal of Organic Chemistry
- Published
- 2024-09-22
- DOI
- https://doi.org/10.1021/acs.joc.4c01702
- Citations
- 1
- Primary Topic
- Chemical Reactions and Isotopes
- Type
- article
- Field-Weighted Citation Impact
- 0.21
Funders
- National Science Foundation
- National Institute of General Medical Sciences
- Division of Chemistry