Stereoselective Synthesis of (<i>Z</i>)‐β‐Thioenamide from (<i>Z</i>)‐Enamide‐Iodines and Thiols under Mild Conditions

Abstract The ( Z )‐β‐thioenamides is a valuable motif in many drugs. However, it's stereoselective synthesis is still facing challenge. Herein, we firstly reported a general and efficient approach for highly stereoselective synthesis of them by using ( Z )‐enamide‐iodines with thiols under transition metal‐free conditions.