Di-μ-adipato-κ<sup>4</sup> <i>O</i> <sup>1</sup>,<i>O</i> <sup>1′</sup>:<i>O</i> <sup>6</sup>,<i>O</i> <sup>6′</sup>-bis[(2,2′-dipyridylamine-κ<sup>2</sup> <i>N</i>,<i>N</i>′)zinc(II)] trihydrate
The title compound, [Zn<sub>2</sub>(C<sub>6</sub>H<sub>8</sub>O<sub>4</sub>)<sub>2</sub>(C<sub>10</sub>H<sub>9</sub>N<sub>3</sub>)<sub>2</sub>]·3H<sub>2</sub>O or {Zn<sub>2</sub>[(C<sub>5</sub>H<sub>4</sub>N)<sub>2</sub>NH]<sub>2</sub>[μ-(CH<sub>2</sub>)<sub>4</sub>(COO)<sub>2</sub>]<sub>2</sub>}·3H<sub>2</sub>O, was separ-ated from the solvothermal reaction of zinc(II) sulfate hepta-hydrate, 2,2'-di-pyridyl-amine and sodium adipate. The dinuclear metal complex has a centrosymmetric structure, with the Zn<sup>II</sup> atom adopting a highly distorted octa-hedral coordination sphere composed of four oxygen atoms from bridging adipato ligands and two pyridine nitro-gen atoms. In the crystal, the title compound aggregates into a tri-periodic supra-molecular structure through inter-molecular hydrogen-bonding networks of the form O-H⋯O and N-H⋯O.
Authors
- Abderezak Addala
- Zouaoui Setifi (ORCID: https://orcid.org/0000-0002-8160-3852)
- Chien Thang Pham (ORCID: https://orcid.org/0000-0003-0619-2720)
- Fatima Setifi (ORCID: https://orcid.org/0000-0002-9860-9310)
- Mohammad Hadi Al-Douh
Institutions
- Vietnam National University, Hanoi (VN)
- Hadhramout University (YE)
- University Ferhat Abbas of Setif (DZ)
- VNU University of Science (VN)
- University of Skikda (DZ)
Publication Details
- Journal
- IUCrData
- Published
- 2024-09-20
- DOI
- https://doi.org/10.1107/s2414314624009064
- Primary Topic
- Metal complexes synthesis and properties
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Direction Générale de la Recherche Scientifique et du Développement Technologique