Photochemical Defluorinative Alkenylation of Trifluoromethyl Alkenes with Organoboronic Acids
Abstract We have developed a photo‐catalyzed defluorinative two‐component coupling reaction of trifluoromethyl alkenes and organoboronic acids, providing a straightforward and efficient route for the synthesis of functionalized gem ‐difluorinated 1,4‐dienes. Both the chemical yields and functional group tolerance are generally good.
Authors
- Bo Xu (ORCID: https://orcid.org/0000-0001-8702-1872)
- Shiyu He (ORCID: https://orcid.org/0000-0003-2383-2072)
Institutions
- Donghua University (CN)
Publication Details
- Journal
- European Journal of Organic Chemistry
- Published
- 2024-09-19
- DOI
- https://doi.org/10.1002/ejoc.202400973
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Science Foundation
- National Natural Science Foundation of China