Copper Catalyzed Fluoroalkyl‐Selenization of Olefins
Abstract An efficient copper catalyzed fluoroalkyl‐selenization reaction of olefins has been developed, providing 1,2‐difluoroarylselenides in moderate to excellent yields. The readily available ethyl bromodifluoroacetate and diphenyl diselenide (Ph 2 Se 2 ) have been employed as efficient radical precursor and selenization reagents to react with olefins. The reaction features a broad substrate scope, including substituted alkenes with various functional groups.
Authors
- Ya-Wen Zuo
- Xi‐Sheng Wang (ORCID: https://orcid.org/0000-0003-2398-5669)
- Ruo‐Xing Jin (ORCID: https://orcid.org/0000-0002-6381-148X)
- Jianliang Yu (ORCID: https://orcid.org/0000-0002-7041-9312)
- Qingqing Zhang (ORCID: https://orcid.org/0000-0002-1464-6203)
- Yifan Zhang (ORCID: https://orcid.org/0000-0003-1298-5436)
Institutions
- University of Science and Technology of China (CN)
Publication Details
- Journal
- ChemCatChem
- Published
- 2024-09-19
- DOI
- https://doi.org/10.1002/cctc.202401395
- Citations
- 1
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.21
Funders
- National Science Foundation
- National Natural Science Foundation of China