Single Exposed Zn (0002) Plane and Sustainable Zn‐Oriented Growth Achieving Highly Reversible Zinc Metal Batteries
To prevent dendrite growth and hydrogen evolution reaction, directional epitaxial growth of Zn<sup>2+</sup> ions on Zn anode, especially along the lowest-surface-energy Zn (0002) plane, is pursued for highly reversible zinc metal batteries (ZMBs). However, designing single Zn (0002) exposed anodes for sustained uniaxial crystalline orientation of Zn electroplating faces challenges. Herein, we propose an anode engineering that utilizes a low lattice mismatch substrate and ordered Zn<sup>2+</sup> migration channels to modify Zn anodes with single (0002) surface exposure and sustainable Zn-oriented growth, yielding highly reversible ZMBs. A vapor-deposited metal-organic framework Cu<sub>3</sub>(C<sub>6</sub>O<sub>6</sub>)<sub>2</sub> film on brass foil shows low lattice mismatch (4.24 %) with electrodeposited Zn anodes, enabling the exposure of a single (0002) plane. Furthermore, the low desolvation energy (-1.36 eV) between solvated Zn<sup>2+</sup> ions and the ordered porous Cu<sub>3</sub>(C<sub>6</sub>O<sub>6</sub>)<sub>2</sub> film guides sustainable Zn-oriented nucleation along the Zn (0002) surface. Consequently, the Zn||Zn cells with brass-Cu<sub>3</sub>(C<sub>6</sub>O<sub>6</sub>)<sub>2</sub> substrate shows a high average Coulombic efficiency of 99.55 % after 4,000 cycles at 10 mA cm<sup>-2</sup>. This work provides a new window to design highly reversible Zn metal anode with a single-exposed Zn (0002) plane and sustainable oriented growth for emerging ZMBs.
Authors
- Yaokang Lv (ORCID: https://orcid.org/0000-0002-0077-9048)
- Ziyang Song (ORCID: https://orcid.org/0009-0006-7510-5159)
- Lihua Gan (ORCID: https://orcid.org/0000-0002-3652-8822)
- Da Zhang (ORCID: https://orcid.org/0000-0002-2613-1354)
- Mingfang Li
- Mingxian Liu (ORCID: https://orcid.org/0000-0002-9517-2985)
- Ling Miao
- Hui Duan (ORCID: https://orcid.org/0000-0003-3886-654X)
Institutions
- Tongji University (CN)
- Zhejiang University of Technology (CN)
Publication Details
- Journal
- Angewandte Chemie International Edition
- Published
- 2024-09-19
- DOI
- https://doi.org/10.1002/anie.202414116
- Citations
- 45
- Primary Topic
- Advanced battery technologies research
- Type
- article
- Field-Weighted Citation Impact
- 9.39
Funders
- National Natural Science Foundation of China
- China Postdoctoral Science Foundation
- Science and Technology Commission of Shanghai Municipality
- Fundamental Research Funds for the Central Universities