Generation and Application of Sulfur Ylides in Light‐Mediated Transformations

Abstract Sulfur ylides are essential reagents in various organic reactions like epoxidation and cyclopropanation. While traditionally employed in ionic chemistry, recent advancements in visible‐light‐driven photocatalysis reveal their potential as sources of radicals or free carbenes. The photochemical or photocatalytic generation of reactive intermediates using sulfur ylides expands the utility of these reagents in modern organic synthesis, offering sustainable solutions to emerging challenges. Despite early demonstrations in the 1960s, the past years have witnessed a surge in photochemical methods utilizing sulfur ylides as precursors. The use of redox‐active photocatalysts has facilitated numerous radical reactions. This review consolidates key findings in sulfur ylide chemistry, particularly focusing on photo‐mediated reactions, to stimulate further research interest in this dynamic field.