Hydrogen Generation by Nickel Electrodes Coated with Linear Patterns of PTFE

Previous studies have shown that partially coating electrode surfaces with patterns of ‘islands’ of hydrophobic tetrafluoroethylene (PTFE; Teflon) may lead to more energy efficient gas generation. This occurred because the gas bubbles formed preferentially on the PTFE, thereby freeing up the catalytically active metallic surfaces to produce the gas more efficiently. This work examined electrochemically induced hydrogen bubble formation on a nickel electrode surface that had been coated with linear patterns of PTFE. The impact of the PTFE line size (width) and degree of coverage was examined and analyzed. No improvement in electrical energy efficiency was observed up to 15 mA/cm2 when comparing the PTFE-coated electrodes with the control bare uncoated electrode. However, increasing PTFE coverage up to 15% generally improved electrolysis performance. Moreover, samples with 50% wider lines performed better (at the equivalent PTFE coverage), yielding an overpotential decline of up to 3.9% depending on the PTFE coverage. A ‘bubble-scavenging’ phenomenon was also observed, wherein bubbles present on the PTFE lines rapidly shrunk until they disappeared.