The Roman villa at the Castle of Baia (Naples, Italy): investigations on the polychromy of frescoed surfaces by using non-destructive spectroscopic techniques

Abstract During the Roman age, the southern promontory of the gulf of Baia was the perfect location for the construction of villae maritimae for the Roman élite that decided to spend their summer residences by the sea. One of these residences is now located in the military fortress of the Castello Aragonese di Baia , built in 1495 CE during the Aragonese period (15 th century). Here, during restoration works, the ruins of the residential sector of the villa, which historical sources ascribe to Caesar, were unearthed. The most representative evidence of this is the outstanding in situ remain of mosaics, decorated plasters and finely frescoed surfaces decorated according to the repertoire of the II style. This research aims to investigate the polychromy of a wall decoration representing a perspective depiction of architectural scenes en trompe l'oeil analysed by means of a multi-analytical, non-destructive approach performed in situ. The combined use of spectroscopic techniques (portable X-ray fluorescence, Raman and Fourier Transform Infrared Spectroscopy) points out the use of a characteristic Roman palette, quantitatively assessed by colorimetric measurements. It consists of red and yellow ochre, calcite, hematite, organic black pigments, precious materials such as cinnabar and Egyptian blue, green copper compounds. Fourier Transform Infrared Spectroscopy also revealed the presence of synthetic resins, likely used for the conservation of mural paintings. These are, however, damaged by atmospheric humidity, as detected by Infrared Thermography. Gypsum has been identified as the main weathering product.