Photoinduced, Redox-Neutral Decyanative and Defluorinative Phosphination of (Hetero)Arenes
Triarylphosphines play a crucial role in organic synthesis as versatile components serving as ligands, catalysts, and reactants. This study introduces a metal-free, visible-light-induced method for the cross-coupling of cyanopyridines or polyfluoroarenes with diarylphosphines. This approach facilitates the formation of C(sp<sup>2</sup>)-P bonds through redox-neutral decyanative or defluorinative process, enabling the convenient synthesis of diverse triarylphosphines.
Authors
- Lan‐Gui Xie (ORCID: https://orcid.org/0000-0001-9577-9704)
- Meizhong Tang
- Shenlin Huang (ORCID: https://orcid.org/0000-0001-7322-6981)
- Yating Wang (ORCID: https://orcid.org/0000-0002-2030-6176)
- Conghui Wang (ORCID: https://orcid.org/0009-0000-5562-2526)
Institutions
- Nanjing Normal University (CN)
- Nanjing Forestry University (CN)
Publication Details
- Journal
- Organic Letters
- Published
- 2024-09-16
- DOI
- https://doi.org/10.1021/acs.orglett.4c03049
- Citations
- 5
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 1.25
Funders
- National Key Research and Development Program of China