Hollow CoFe Oxide Prisms for Cross-Dehydrogenative Coupling Reactions of 1,2,3,4-Tetrahydroisoquinolines under Mild Conditions
A three-dimensional hollow CoFe oxide prism catalyst was successfully prepared via a self-template strategy. This bimetallic oxide catalyst demonstrated excellent catalytic activity in cross-dehydrogenative coupling reactions of 1,2,3,4-tetrahydroisoquinolines under mild conditions compared to its monometallic oxide counterparts. A preliminary mechanistic investigation showed the involvement of reactive oxygen species, produced from molecular O<sub>2</sub> by the active bimetallic oxide catalyst in the catalytic cycle.
Authors
- Yuxing Huang (ORCID: https://orcid.org/0000-0001-6012-8100)
- Mauro Carraro (ORCID: https://orcid.org/0000-0002-1194-6147)
- Troels Skrydstrup (ORCID: https://orcid.org/0000-0001-8090-5050)
- Mingdong Dong (ORCID: https://orcid.org/0000-0002-2025-2171)
- Xin Zhuo (ORCID: https://orcid.org/0000-0001-7681-819X)
- Kim Daasbjerg (ORCID: https://orcid.org/0000-0003-0212-8190)
- Qing Liu (ORCID: https://orcid.org/0000-0003-2745-3440)
- Hui Xu (ORCID: https://orcid.org/0000-0002-1744-4180)
- Jianyao Kou
Institutions
- University of Padua (IT)
- Nanchang University (CN)
- Aarhus University (DK)
- Novo Nordisk Foundation (DK)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2024-09-17
- DOI
- https://doi.org/10.1021/acs.inorgchem.4c03061
- Citations
- 3
- Primary Topic
- Catalytic C–H Functionalization Methods
- Type
- article
- Field-Weighted Citation Impact
- 0.75
Funders
- National Natural Science Foundation of China
- Ministry of Education of the People's Republic of China
- Government of Jiangxi Province
- Natural Science Foundation of Jiangxi Province
- Novo Nordisk Fonden