Dental composite materials based on <scp>Z</scp>n/<scp>A</scp>l‐layered double hydroxide and their physical mechanical properties

Abstract Dental materials' demands can be answered using composite materials, as composite properties are suitable for tailoring the material's behavior. Poly (methyl methacrylate) (PMMA) is usually a material of choice in dental applications, and its mechanical properties can be improved in terms of modulus, strength, and hardness. The chosen reinforcement in this publication was Zn/Al‐layered double hydroxide (LDH), as this material has functional property modification possibilities. The reinforcement was synthesized using the coprecipitation process on a laboratory scale. The dispersion of the reinforcement was done with ultrasonication, and the composites prepared contained 1, 3, and 5 wt% of reinforcement, and the so‐prepared composites were compared to the matrix. Improvements were observed in terms of the elastic modulus and tensile strength, and the best performance was observed in the composite with 3 wt% of particles. Hardness increased with the addition of particles and the higher the particle content, the better the hardness. Materials were tested using dynamic mechanical techniques, and it was proven that the addition of particles lowers the Tg of the composite compared to the pure matrix. The addition of particles diminished the affinity of the material for polar liquids such as water. Highlights Zn/Al‐layered double hydroxide is used to reinforce acrylic matrix. Composite with improved strength, modulus, and microhardness. Addition of a layered double hydroxide decreases hydrophobicity of composite.