Biogenic Volatile Organic Compound Emission and Its Response to Land Cover Changes in China During 2001–2020 Using an Improved High‐Precision Vegetation Data Set

Abstract Biogenic volatile organic compounds (BVOCs) are regarded as important precursors for ozone and secondary organic aerosol, mainly from vegetation emissions. In the context of the expanding trend of vegetation greening, the development of high‐precision vegetation data and accurate BVOC emission estimates are essential to develop effective air pollution control measures. In this study, by integrating the multi‐source vegetation cover data, we established a high‐resolution vegetation distribution (HRVD) data set to develop a high spatio‐temporal resolution emission inventory and investigated the impact of different land cover data sets on emission simulation and impact of land cover change on BVOC emissions during 2001–2020. The annual total BVOC emissions in China for 2020 was 15.66 Tg, which were mainly from trees. The emissions simulated by CNLUCC and MODIS data sets were 1.53% and 1.72% higher than those simulated by HRVD data sets, respectively. The spatial distribution of emission differences was consistent with that of land cover differences. The simulated BVOC emissions by the HRVD data set had the best accuracy as they improved the bias between modeling and observation from 69.06% to 65.35% and decreased the underprediction of observations by a factor of 2.13 compared with simulation by MEGAN default vegetation data. The annual BVOC emissions caused by changing vegetation distribution and LAIv (LAI of vegetation covered surfaces) enhanced at a rate of 72.06 Gg yr −1 during 2001–2020. LAIv was the main driver of emission variations. The total OH reactivity of the resulted BVOC emissions increased at a rate of 1.59 s −1 yr −1 , with isoprene contributed the most.