Synthesis, characterization and application of quinoxaline-based organic dyes as anodic sensitizers in photoelectrochemical cells

Three new D-A-π-A organic dyes ( 1a-c ) containing a 2,3-diphenylquinoxaline core as the main chromophore were designed to act as sensitizers for the TiO 2 -based photoanode of dye-sensitized photoelectrochemical cells (DS-PEC) for water splitting. The dyes structures featured a cyanoacrylic acid group as the terminal acceptor/anchoring moiety and three different donor groups of moderate strength, namely mono- and dialkoxy-substituted benzenes, which were introduced to modulate the energies of the respective HOMO levels and enable the electron transfer from a Ru-based molecular water oxidation catalyst (WOC). Dyes 1a-c were synthesized following a C–H activation strategy and fully characterized. In addition, the previously known catalyst Ru(bda)(PyP) 2 (bda = 2,2′-bipyridine-6,6′-dicarboxylate; PyP = pyridin-4-methyl phosphonic acid) was also prepared by modification of a reported procedure. The dynamics of charge transfer processes involving the dyes adsorbed on nanocrystalline TiO 2 films were investigated by means of transient absorption spectroscopy. Photo-electrochemical experiments carried out on photoanodes functionalized with 1a-c and Ru(bda)(PyP) 2 in 0.1 M aq. Na 2 SO 4 electrolyte showed the production of photocurrents up to ca. 0.15 mA cm −2 at + 0.5 V vs. NHE, and highlighted how modifications of the TiO 2 staining procedure can lead to significant differences in cell performances.