Selective capture of iodate anions by a cerium-based metal-organic framework

<p indent="0mm">Effective remediation of radioactive IO₃⁻ is highly desirable for fuel reprocessing, medical waste disposal, and nuclear accidents. However, the nature of high solubility, strong mobility, and extremely hard to bind with minerals for IO₃⁻ makes this task an enormous challenge. Herein, a metal-organic framework material [Ce(IV)-MOF-808] with available Ce(IV) sites was used to efficiently remove IO₃⁻. Ce(IV)-MOF-808 exhibits superior selectivity and one of the highest adsorption capacities <sc>(623 mg·g⁻¹)</sc> for IO₃⁻ removal. Moreover, Ce(IV)-MOF-808 shows great adsorption performance for IO₃⁻ at low concentrations, and the distribution coefficient (<italic>K_d</italic>) value was calculated to be 2.60 × <sc>10⁶ mL·g⁻¹.</sc> The exceptional IO₃⁻ uptake performance is attributed to the high affinity between Ce(IV) cluster and the oxyanion based on the comprehensive analysis of zeta potential and X-ray photoelectron spectroscopy (XPS) results, in which IO₃⁻ can easily replace the weakly coordinated ligand and form a strong coordination structure of Ce-O-I-O₂. More importantly, Ce(IV)-MOF-808 exhibits excellent uptake performance for IO₃⁻ from both the simulated Beishan groundwater system and Hanford groundwater system in the dynamic column separation test, indicating the highly promising practical application of Ce(IV)-MOF-808 in IO₃⁻ remediation from actual radioactive wastes.