Environmental transport and sorting of glass retroreflective microbeads and their potential as proxies for road marking paints

Road marking paints are a potentially important contributor to the global microplastic pool but very little reliable information is available on their erosion or environmental distributions. As potential carriers of or proxies for road paints, we determine the concentrations and sorting of retroreflective glass microbeads in marking materials and in fractionated (< 5 mm) local dusts, soils and sediments. As an aid to our investigation, we also determine the concentrations of metals of geochemical significance or components of road paint pigments in markings and geosolids. Concentrations of beads up to 92,800 kg^-1 were observed in street dusts, with a median diameter (350 μm) greater than that in road marking samples (270 μm). Few beads were found in adjacent (< 5 m) or more remote soils (six beads in ten 50-g samples) and none were detected in replicates of a sample of roof dust, suggesting that aeolian transport is limited. Concentrations up to 3700 kg^-1 were found in estuarine sediments close to bridges or stormwater runoff effluents, and with increasing sediment depth concentrations and median diameter decreased; beads were not, however, detected in sediments 400 m away from any significant roads or runoff effluents. These observations suggest that bead accumulation is constrained locally but that the precise distance travelled and extent of burial in sediments are inversely related to size. Road marking paints sampled from urban streets readily fragmented into pieces smaller than glass microbeads, suggesting that while beads might carry small quantities of paint, transport and dispersion of the two particle types may not be directly coupled. Environmental ratios of V to Bi and Cr to Pb, as markers for BiVO₄- and PbCrO₄-pigmented yellow paints, respectively, did not correlate with bead distribution, presumably because these metals have a multitude of additional anthropogenic sources. However, an inverse relationship between bead concentrations and K:Ca suggests that this ratio might be a useful proxy of road marking paint in regions that are geologically similar.