Ruthenium(II)-Catalyzed C–H Allylation of N,N-Dialkylthiobenzamides with Allyl Methyl Carbonate by Sulfur Coordination
Abstract This report describes a Ru(II)-catalyzed C–H allylation of N,N-dialkylthiobenzamides with allyl methyl carbonate. The reaction is carried out using [RuCl2(p-cymene)]2 in the presence of Cu(OAc)2 and Ag2O. This method represents the first example of a Ru-catalyzed C–H allylation directed by a sulfur-containing group. As a further advantage, the method is performed in sustainable and ecofriendly MeCN as the solvent.
Authors
- Rong Zhang (ORCID: https://orcid.org/0000-0002-7103-2996)
- Liang Zhao (ORCID: https://orcid.org/0000-0001-8197-6686)
- Chunying Duan (ORCID: https://orcid.org/0000-0003-1638-6633)
- Jin Kun (ORCID: https://orcid.org/0000-0003-4038-3213)
- Yaming Li (ORCID: https://orcid.org/0000-0001-6265-1982)
- Runbao Wang
Institutions
- Dalian University of Technology (CN)
- Dalian University (CN)
Publication Details
- Journal
- Synlett
- Published
- 2024-09-13
- DOI
- https://doi.org/10.1055/a-2415-3708
- Primary Topic
- Catalytic C–H Functionalization Methods
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China
- Natural Science Foundation of Liaoning Province
- Fundamental Research Funds for the Central Universities