Cadmium(II) Complexes with Redox-Active Indophenol Ligands: Synthesis and Structures

The Сd(II) complexes with redox amphoteric 2,6-di-(tret-butyl)-4-((2-hydroxyphenyl) imino)cyclohexa-2,5-dienone ligands L1 and L2 (adducts I, II, and III) are synthesized. The structures of coordinated complexes I, II, and III are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 1838319 (II) and 1838310 (III)) and confirmed by the 1Н, 13С, and 113Cd NMR spectroscopy (for complexes I and III) and IR spectroscopy data.

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Publication Details

Journal
Координационная химия
Published
2024-09-12
DOI
https://doi.org/10.31857/s0132344x24040017
Primary Topic
Metal complexes synthesis and properties
Type
article
Field-Weighted Citation Impact
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article

Cadmium(II) Complexes with Redox-Active Indophenol Ligands: Synthesis and Structures

Pavel A. Knyazev, Владимир И. Минкин, Г. С. Бородкин, E. P. Ivakhnenko et al.
Координационная химия
Metal complexes synthesis and properties
article

Cadmium(II) Complexes with Redox-Active Indophenol Ligands: Synthesis and Structures

Pavel A. Knyazev, Владимир И. Минкин, Г. С. Бородкин, E. P. Ivakhnenko, Yu. G. Vitkovskaya, N. I. Merezhko, К. А. Лысенко
article en

Abstract

The Сd(II) complexes with redox amphoteric 2,6-di-(tret-butyl)-4-((2-hydroxyphenyl) imino)cyclohexa-2,5-dienone ligands L1 and L2 (adducts I, II, and III) are synthesized. The structures of coordinated complexes I, II, and III are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 1838319 (II) and 1838310 (III)) and confirmed by the 1Н, 13С, and 113Cd NMR spectroscopy (for complexes I and III) and IR spectroscopy data.

Координационная химияVol. 50(4)
Southern Federal University (RU), Institute of Physical and Organic Chemistry (BY)
Openalex Percentile: Top 74%
Metal complexes synthesis and properties
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