Influence of the Eliminated Ligand Structure on the Reduction Rate of the Cobalt(III) Complexes
The reduction of the heteroleptic cobalt(III) complexes with bipyridine ligands of different structures of the model drug molecule is studied by in situ NMR spectroscopy. The nature of the ligand eliminated during reduction is shown to exert a substantial effect on the reduction rate, which indicates that an optimum amount of cobalt should be chosen for the redox-activated delivery of a certain drug.
Authors
- Ekaterina A. Khakina (ORCID: https://orcid.org/0000-0001-6194-5073)
- И. А. Никовский
- Anastasia A. Danshina (ORCID: https://orcid.org/0000-0003-0368-2177)
- Yulia Vladimirovna Nelyubina (ORCID: https://orcid.org/0000-0002-9121-0040)
- К. А. Spiridonov (ORCID: https://orcid.org/0000-0002-9930-9977)
Institutions
- Moscow Institute of Physics and Technology (RU)
- Moscow Power Engineering Institute (RU)
- A. N. Nesmeyanov Institute of Organoelement Compounds (RU)
- Moscow Aviation Institute (RU)
Publication Details
- Journal
- Координационная химия
- Published
- 2024-09-12
- DOI
- https://doi.org/10.31857/s0132344x24040039
- Primary Topic
- Metal complexes synthesis and properties
- Type
- article
- Field-Weighted Citation Impact
- 0.00