Utilizing ESI‐MS/MS and ion mobility spectrometry for structural characterization and isomer differentiation of 1, 2‐unsaturated (1‐4) linked disaccharide derivatives and their 2‐ <i>C</i> ‐functionalized analogues
ESI CID spectra of [M + Li]<sup>+</sup> adduct ions for individual glycal disaccharide analogues facilitate the discrimination between alpha and beta (1-4) linked unsaturated disaccharides and their 2-C-branched analogues. Through optimized experimental conditions, complete baseline ion mobility separation of stereoisomer pairs of the Cs adducts is achieved.
Authors
- I. Starke (ORCID: https://orcid.org/0000-0001-5751-8618)
- Sylvia Fürstenberg
- St. Thomas (ORCID: https://orcid.org/0000-0002-8039-4366)
Institutions
- University of Potsdam (DE)
Publication Details
- Journal
- Rapid Communications in Mass Spectrometry
- Published
- 2024-09-12
- DOI
- https://doi.org/10.1002/rcm.9899
- Primary Topic
- Mass Spectrometry Techniques and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Universität Potsdam