Pulsed electroplating of ZrO2-reinforced Ni-Cr alloy coatings from the duplex complexing agents-containing bath for engineering applications: Importance of operating conditions

The progress in tribocorrosion performance of the engineering parts is in dire need of improving their surface properties. In the present contribution, Ni-Cr-ZrO₂ layers were electrodeposited on St37 steel. The stress was put on optimizing the process factors, including the parameters involved in pulsed current electrodeposition and level of the ZrO₂ reinforcing nanoparticles (0-20 g/L) in the bath. The surface characteristics of the electrodeposits were evaluated using FESEM, EDS, AFM, and XRD. The tribomechanical characteristics of the films were determined using a Vickers microhardness tester and pin-on-disk apparatus. The electrochemical behavior of the samples was studied using OCP, EIS, PDP, and immersion techniques. The results demonstrated that the included ZrO₂ nanoparticles led to more homogenous, rougher, and defect-free surfaces, while they did not change the phase composition of the alloy electrodeposits. The polarization resistance of the Ni-Cr alloy coating increases by 6.7 times when 10 g/L of the reinforcing nanoparticles is added to the electrolyte. A decrease of ≈42 % in the mean COF value was obtained by the incorporation of 10 g/L ZrO₂ nanoparticles into the plating bath. The coating system developed holds the promise to address both technical requirements and health concerns.