Green‐Light Hydrosilylation Photocatalysis with Platinum(II)Metalla‐N‐Heterocyclic Carbene Complexes
Platinum(II) metalla-N-heterocyclic carbene complexes featuring pyridyl heterocyclic moiety demonstrate remarkable catalytic efficiency in alkyne hydrosilylation under green light irradiation. The photocatalytic properties of complexes are rationalised by the photo-induced charge transfer occurring in extended condensed system identified with the help of various experimental (UV/vis and emission spectroscopy, cyclic voltammetry) and theoretical methods (DFT/TD-DFT, IFCT analysis).
Authors
- Maria V. Kashina (ORCID: https://orcid.org/0000-0002-3063-3074)
- Konstantin V. Luzyanin (ORCID: https://orcid.org/0000-0001-9312-7139)
- Mikhail A. Kinzhalov (ORCID: https://orcid.org/0000-0001-5055-1212)
- Eugene A. Katlenok (ORCID: https://orcid.org/0000-0002-4485-7247)
Institutions
- University of Liverpool (GB)
- St Petersburg University (RU)
Publication Details
- Journal
- Chemistry - A European Journal
- Published
- 2024-09-10
- DOI
- https://doi.org/10.1002/chem.202403264
- Citations
- 6
- Primary Topic
- Catalytic C–H Functionalization Methods
- Type
- article
- Field-Weighted Citation Impact
- 1.50
Funders
- Ministry of Science and Higher Education of the Russian Federation
- Division of Materials Research