Electrochemical Carboarylation of Activated Alkenes with <scp>CO<sub>2</sub></scp> and Electron‐deficient Aryl Bromides
Comprehensive Summary The simultaneous construction of two vicinal C—C bonds in a molecule remains a significant challenge. In this work, we disclose an electroreductive carboarylation of activated alkenes under mild, transition metal‐free conditions. Utilizing readily available starting materials (electron‐deficient aryl bromides, activated alkenes, and CO 2 ), this method demonstrates broad substrate scope and good functional group tolerance. Notably, this strategy enables the addition of two distinct electrophiles across an alkene in a highly chemo‐ and regioselective manner.
Authors
- Shengzhang Liu
- Hong Yi (ORCID: https://orcid.org/0000-0002-3337-1452)
- Aiwen Lei (ORCID: https://orcid.org/0000-0001-8417-3061)
- Cheng Ming Zhong (ORCID: https://orcid.org/0000-0003-1852-5860)
- Jianye Zhang (ORCID: https://orcid.org/0000-0002-3801-7890)
- Chunlei Liu (ORCID: https://orcid.org/0000-0001-8816-4832)
- Zhaoliang Yang (ORCID: https://orcid.org/0009-0003-5498-6055)
- Mingming Yu (ORCID: https://orcid.org/0009-0007-4705-7548)
- Yangyang Li (ORCID: https://orcid.org/0000-0001-7052-8909)
Institutions
- Jiangxi University of Traditional Chinese Medicine (CN)
- Zhejiang Sci-Tech University (CN)
- Wuhan University (CN)
- Jiangxi Normal University (CN)
Publication Details
- Journal
- Chinese Journal of Chemistry
- Published
- 2024-09-10
- DOI
- https://doi.org/10.1002/cjoc.202400661
- Citations
- 10
- Primary Topic
- CO2 Reduction Techniques and Catalysts
- Type
- article
- Field-Weighted Citation Impact
- 1.02